How To Change Primary Email Address In Active Directory?
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1. Open Active Directory Users and Computers on the Domain Controller.
2. Right–click the user account that contains the primary email address you want to change.
3. Click Properties.
4. Select the Email Addresses tab.
5. Click the Remove button next to the Primary Email address.
6. Click the Add button at the bottom of the window.
7. Enter the new primary email address.
8. Click OK to save the changes.